[(E)-cinnamyl]-triphenyl-phosphonium chloride → Cinnamyltriphenylphosphonium tetrafluoroborate

HRID 274194

반응식

HRID 274194 반응식
[Cl-].[CH2:2]([P+:11]([C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1)([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[CH:3]=[CH:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.[F:30][B-:31]([F:34])([F:33])[F:32].[Na+]>O>[F:30][B-:31]([F:34])([F:33])[F:32].[CH2:2]([P+:11]([C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1)([C:12]1[CH:13]=[CH:14][CH:15]=[CH:16][CH:17]=1)[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[CH:3]=[CH:4][C:5]1[CH:6]=[CH:7][CH:8]=[CH:9][CH:10]=1

참가 물질

4

반응물 2

HCID 73729[(E)-cinnamyl]-triphenyl-phosphonium chlorideHCID 4343483Sodium Tetrafluoroborate

생성물 1

HCID 72739364Cinnamyltriphenylphosphonium tetrafluoroborate

시약·촉매·용매 1

HCID 962Water용매2회

실험 절차

10.4 parts of cinnamyltriphenylphosphonium chloride prepared in the above Synthetic Example 2 was dissolved in 580 parts of water and a solution of 2.7 parts of sodium tetrafluoroborate in 9 parts of water was slowly added dropwise thereto. After 6 hr stirring, the resulting colorless crystals were collected by filtration, washed with 300 parts of water, and dried to obtain 10.1 parts of cinnamyltriphenylphosphonium tetrafluoroborate (compound No. 5).

후처리

  1. filtrationthe resulting colorless crystals were collected by filtration
  2. washwashed with 300 parts of water
  3. customdried

출처 및 근거

ORD 기록
ord-67f66f067c0c4272bda2b0c3e13dbf7f
출처 데이터셋
uspto-grants-1995_02
특허 번호
US05389486

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