Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Triethyl Citrate → 2-(Oxolan-3-yl)ethan-1-ol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Triethyl Citrate | HCID 6506 | — |
| 반응물 | Tetrahydrofuran | HCID 8028 | — |
| 반응물 | HCID 178418361 | HCID 178418361 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | (Oxan-4-yl)methanol | HCID 2773573 | 3.6% |
| 생성물 | 2-(Oxolan-3-yl)ethan-1-ol | HCID 11126225 | 49% |
반응 단계
400 ml of triethyl citrate were hydrogenated at 225° C. and 200 bar together with 1100 ml of tetrahydrofuran and 60 g of catalyst H (3-mm tablets) until the take-up of hydrogen had ceased. The reaction product was freed from tetrahydrofuran and ethanol and distilled under reduced pressure, giving 93.6 g (49%) of 3-(2'-hydroxyethyl)tetrahydrofuran and 6.8 g (3.6%) of 4-hydroxymethyltetrahydropyran.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05391771 |
| 출처 데이터셋 | uspto-grants-1995_02 |
| ORD ID | ord-e0c800179a6a41f3800b0b39c6564e34 |
| 출처 메모 | uspto-grants-1995_02 |