Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Triethyl Citrate → Ethyl tetrahydrofurfurylacetate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Triethyl Citrate | HCID 6506 | — |
| 반응물 | Tetrahydrofuran | HCID 8028 | — |
| 반응물 | HCID 178418361 | HCID 178418361 | — |
| 생성물 | Ethyl tetrahydrofurfurylacetate | HCID 263175 | 39% |
| 생성물 | 2-(Oxolan-3-yl)ethan-1-ol | HCID 11126225 | 30% |
반응 단계
400 ml of triethyl citrate were hydrogenated at 175° C. and 50 bar together with 1100 ml of tetrahydrofuran and 60 g of catalyst F (4-mm tablets) until the take-up of hydrogen had ceased. The reaction product was freed from tetrahydrofuran and distilled under reduced pressure, giving 101 g (39%) of ethyl tetrahydrofurfurylacetate and 57 g (30%) of 3-(2'-hydroxyethyl)tetrahydrofuran.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05391771 |
| 출처 데이터셋 | uspto-grants-1995_02 |
| ORD ID | ord-b5ff5c4a485e45258089b7c7e10d1743 |
| 출처 메모 | uspto-grants-1995_02 |