2-Chlorophenol → Phenol, 2-bromo-6-chloro-

HRID 27799

반응식

HRID 27799 반응식
[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[OH:8].[Br:9]Cl>C(Cl)(Cl)(Cl)Cl>[Br:9][C:4]1[CH:5]=[CH:6][CH:7]=[C:2]([Cl:1])[C:3]=1[OH:8].[Br:9][C:6]1[CH:5]=[CH:4][C:3]([OH:8])=[C:2]([Cl:1])[CH:7]=1

참가 물질

5

반응물 2

HCID 72452-ChlorophenolHCID 61697BROMINE CHLORIDE (BrCl)

생성물 2

HCID 16268Phenol, 2-bromo-6-chloro-HCID 198594-Bromo-2-chlorophenol

시약·촉매·용매 1

HCID 5943Carbon Tetrachloride용매

실험 절차

Furthermore, it is known from the U.S. Pat. No. 3,449,443 that on reaction of 2-chlorophenol with bromine chloride in carbon tetrachloride at 0° C. there is formed, besides 74% of theory of 2-bromo-6-chlorophenol, only 22% of theory 4-bromo-2-chlorophenol; and at 23° to 26° C. there is formed, besides 61.7% of theory of 2-bromo-6-chlorophenol, only 26.3% of theory of 4-bromo-2-chlorophenol.

출처 및 근거

ORD 기록
ord-e8ca51cde7a846a09d8c33e013cebafc
출처 데이터셋
uspto-grants-1980_09
특허 번호
US04223166

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