1-Bromohexane → HCID 11732181, 화합물

HRID 279422노트

반응식

HRID 279422 반응식
[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[CH2:5][C:4]=2[CH:3]=1.Br[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]>>[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[C:5]([CH2:13][CH2:14][CH2:2][CH2:3][CH2:4][CH3:12])([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[C:4]=2[CH:3]=1

참가 물질

3

반응물 2

HCID 81011-BromohexaneHCID 2519872,7-Dichlorofluorene

생성물 1

HCID 11732181HCID 11732181, 화합물수율 91%

실험 절차

2,7-Dichloro-9,9-di(1-hexyl)fluorene is prepared from 2,7-dichiorofluorene and 1-bromohexane following the procedure of Example 1 as colorless crystals (recrystallized from hexane) in 91 percent yield, melting point 66° C. to 67° C. HPLC analysis shows that the sample is 99 percent or greater pure and the spectral data confirms the title structure.

후처리

  1. customas colorless crystals (recrystallized from hexane) in 91 percent yield, melting point 66° C. to 67° C

출처 및 근거

ORD 기록
ord-42c0d486356c4c6baf54230a0da82d5f
출처 데이터셋
uspto-grants-2002_03
특허 번호
US06362310B1

반응 노트

불러오는 중…