Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Methane → Cyclohexyl isocyanate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Methane | HCID 297 | — |
| 반응물 | 1-Naphthol | HCID 7005 | — |
| 반응물 | Cyclohexylamine | HCID 7965 | — |
| 촉매 | Tetraethylammonium Iodide | HCID 6225 | — |
| 촉매 | Rhodium | HCID 23948 | — |
| 생성물 | Cyclohexyl isocyanate | HCID 18502 | — |
반응 단계
The carbonylation reaction is conducted in the same manner as in Example 1 except that 25 mmol of cyclohexylamine, 86 g of α-naphthol, 1.5 g of Rh/C having 5% Rh carried on activated charcoal and 1 mmol of tetraethylammonium iodide are employed. As a result, the yields of cyclohexyl isocyanate and α-naphthyl cyclohexyl carbamate are 58% and 10%, respectively.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04587056 |
| 출처 데이터셋 | uspto-grants-1986_05 |
| ORD ID | ord-df5d85d8c97f4f9bbfa76d696c7c7942 |
| 출처 메모 | uspto-grants-1986_05 |