Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Methyl carbazate → N-(methoxycarbonyl)-N'-[2-(p-chlorophenylmethylene)-cyclohexylidene]-hydrazine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Methyl carbazate | HCID 80519 | — |
| 반응물 | 2-(p-Chlorophenylmethylene)-cyclohexan-1-one | HCID 286707 | — |
| 용매 | Isopropanol | HCID 3776 | — |
| 생성물 | N-(methoxycarbonyl)-N'-[2-(p-chlorophenylmethylene)-cyclohexylidene]-hydrazine | HCID 57093055 | 93.2% |
반응 단계
33.32 g (0.151 moles) of 2-(p-chlorophenylmethylene)-cyclohexan-1-one and 13.5 g (0.151 moles) of N-methoxycarbonyl hydrazine are dissolved in 230 ml of isopropanol. The reaction mixture is boiled for a few hours, then cooled, clarified with activated carbon, filtered, the filtrate is cooled and the separated crystals are filtered off. 41.2 g of the named compound are obtained. Yield: 93.2%. M.p.: 160.5°-162° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04587261 |
| 출처 데이터셋 | uspto-grants-1986_05 |
| ORD ID | ord-d9a59a7b2137424c8e6008b1a00594a3 |
| 출처 메모 | uspto-grants-1986_05 |