Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzene → Tetraethylammonium 4-Nitrophenolate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzene | HCID 241 | — |
| 반응물 | 4-Nitrophenol | HCID 980 | — |
| 반응물 | Tetraethylammonium Hydroxide | HCID 6509 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | Tetraethylammonium 4-Nitrophenolate | HCID 23322207 | 94.7% |
반응 단계
A mixture of 4-nitrophenol (13.9 g, 0.10 mol) and benzene (250 mL) was treated with tetraethylammonium hydroxide (14.7 g, 0.10 mol), added as a 20% aqueous solution. The mixture was heated under reflux until all water was removed by azeotropic distillation. The solution was allowed to cool with continued stirring. Upon standing, 25.4 g of a yellow solid was obtained; it was recrystallized from THF. 1H NMR (CDCl3) confirmed the title compound.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04588795 |
| 출처 데이터셋 | uspto-grants-1986_05 |
| ORD ID | ord-ee8ea755095f40dfa79c74726b8d381f |
| 출처 메모 | uspto-grants-1986_05 |