1,2-Phenanthrenedione → 1,2-Naphthoquinone

반응식

CC1C(/C=C/C(C)=O)C(C)(C)CCC=1.[C:15]1(=[O:30])[C:28]2[CH:27]=[CH:26][C:25]3[C:20](=CC=CC=3)[C:19]=2[CH:18]=[CH:17][C:16]1=[O:29]>>[CH:25]1[CH:20]=[C:19]2[CH:18]=[CH:17][C:16]([C:15](=[O:30])[C:28]2=[CH:27][CH:26]=1)=[O:29]

참가 물질

반응물 2

HCID 30805661,2-Phenanthrenedione

HCID 5282108Alpha-Ionone

생성물 1

HCID 106671,2-Naphthoquinone

실험 절차

In order to test and evaluate the equipment and methods of the present invention, pre-coated 10 cm×10 cm HPTLC plates (Whatman) and test compounds α-ionone, phenanthrenequinone and 1,2-naphthaquinone (Aldrich) were obtained. The test compounds were initially diluted with acetone to about 10 mg/ml and stock solutions stored below 4° C. The stock solutions were further diluted with acetone just before use. Ceric sulfate prepared by adding 42 g of (NH4)4Ce(SO4)4 and 56 ml of conc. H2SO4 in 1 liter of distilled water was the chromogenic reagent.

출처 및 근거

ORD 기록: ord-c0c231f249374e189fbc6c34c3d16dc3
출처 데이터셋: uspto-grants-1986_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04591272

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