Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Trimethyl phosphite → Phosphinecarboxylic acid, dimethoxy-, cyclohexyl ester, oxide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Trimethyl phosphite | HCID 8472 | — |
| 반응물 | Carbonochloridic acid, cyclohexyl ester | HCID 83262 | — |
| 생성물 | Phosphinecarboxylic acid, dimethoxy-, cyclohexyl ester, oxide | HCID 512109 | — |
반응 단계
From 24.8 g (0.20 mole) of trimethylphosphite and 32.1 g (0.20 mole) of cyclohexylchloroformate, (Y. Iwakura and A. Nabeya, J. Org. Chem. 25 (1960) 1118; M. E. Fourneau et al. Chem. Abstr. 16 (1922) 240; J. H. Saunders et al. J. Am. Chem. Soc. 73 (1951) 3797). (100° C., 2 hours). Yield 30 g (54%). Bp1.4-1.8 148°-151° C. nD21 1.4543.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04591583 |
| 출처 데이터셋 | uspto-grants-1986_05 |
| ORD ID | ord-3ad9619f081b468097b01c8370df9cbf |
| 출처 메모 | uspto-grants-1986_05 |