Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzyl Alcohol → Benzoic Acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzyl Alcohol | HCID 244 | — |
| 반응물 | Sodium periodate | HCID 23667635 | — |
| 촉매 | Ruthenium dioxide | HCID 82848 | — |
| 용매 | Sodium Hydroxide | HCID 14798 | — |
| 생성물 | Benzoic Acid | HCID 243 | 89% |
반응 단계
To a stirred suspension of 20 g (94 m mol) sodium periodate in 200 cc of 1 molar sodium hydroxide there was added 0.1 g (0.75 m mol) ruthenium dioxide and 4.32 g (40 m mol) benzyl alcohol. After two hours the reaction was stopped. The mixture was then filtered and the filtrate washed with ether obtaining a neutral fraction comprising benzaldehyde and unreacted benzyl alcohol. The aqueous alkali phase was acidified with sulfuric acid and extracted with ether. There was obtained 4.32 grams of benzoic acid (89% yield).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04225694 |
| 출처 데이터셋 | uspto-grants-1980_09 |
| ORD ID | ord-6ede1a92eed94cd3931b64ec1fd29d22 |
| 출처 메모 | uspto-grants-1980_09 |