참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Sorbitol | HCID 5780 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | Isosorbide | HCID 12597 | 42.4% |
반응 단계
Sorbitol (25.21 g) was dissolved in water (500 ml) and then transferred to a 1 L autoclave reactor vessel. The catalyst, MFI-40 (HZSM-5 zeolite, 5.02 g), was added. After flushing three times with hydrogen, pressure was set to 300 psi and the reactor was heated with stirring to 280° C. The pressure increased to 1100 psi with heating. Timing began when the reactor reached 280° C. After 30 minutes a 42.4% yield of isosorbide (calculated as mol isosorbide produced/mol starting sorbitol) was obtained.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US07420067B2 |
|---|
| 출처 데이터셋 | uspto-grants-2008_09 |
|---|
| ORD ID | ord-6664c497811a452b9628c86e54eaa2d4 |
|---|
| 출처 메모 | uspto-grants-2008_09 |
|---|
