Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Carbon Dioxide → 2-Mercapto-3-isopropylbenzoic acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Carbon Dioxide | HCID 280 | — |
| 반응물 | N,N,N',N'-Tetramethylethylenediamine | HCID 8037 | — |
| 반응물 | Benzenethiol, 2-(1-methylethyl)- | HCID 96003 | — |
| 반응물 | Butyllithium | HCID 178418339 | — |
| 용매 | Cyclohexane | HCID 8078 | — |
| 생성물 | 2-Mercapto-3-isopropylbenzoic acid | HCID 10655507 | — |
반응 단계
To a solution of 1.0 mmol 2-isopropylthiophenol and 2.2 mmol TMEDA in 2 mL cyclohexane was added 2.2 mmol n-BuLi. Then after stirring 24 h it was added to solid CO2 and stirred for 16 h when extraction and chromatography provided 2-mercapto-3-isopropylbenzoic acid. The methyl ester of this was treated as in example 3 to provide the title compound.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05731432 |
| 출처 데이터셋 | uspto-grants-1998_03 |
| ORD ID | ord-8bfebd9748154a9780039335f8d6e481 |
| 출처 메모 | uspto-grants-1998_03 |