Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sodium hydride → Trimethylsilylethoxymethyltetrazole
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sodium hydride | HCID 24758 | — |
| 반응물 | 2-Chloromethyl 2-(trimethylsilyl)ethyl ether | HCID 2724271 | — |
| 반응물 | HCID 178418441 | HCID 178418441 | — |
| 용매 | Dimethylformamide | HCID 6228 | — |
| 생성물 | Trimethylsilylethoxymethyltetrazole | HCID 178418485 | — |
반응 단계
To a Suspension of 1.1 mmol NaH in 5 mL DMF at 0° C. was added a solution of 1.0 mmol tetrazole in 2 mL DMF. After 30 min, trimethylsilylethoxymethylchloride was added and the mixture stirred for 16 h. Extraction and chromatography provided trimethylsilylethoxymethyltetrazole as an oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05731432 |
| 출처 데이터셋 | uspto-grants-1998_03 |
| ORD ID | ord-dfbffeb92a874b419566deb178159f88 |
| 출처 메모 | uspto-grants-1998_03 |