참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Cyclooctylamine | HCID 2903 | — |
| 반응물 | N-methyl-2-pyrrolidone | HCID 13387 | — |
| 반응물 | Trimesoyl chloride | HCID 78138 | — |
| 반응물 | Lithium Chloride | HCID 433294 | — |
| 용매 | Pyridine | HCID 1049 | — |
| 생성물 | 1,3,5-Benzenetricarboxylic acid tris(cyclooctylamide) | HCID 59789613 | — |
반응 단계
4.20 g (33 mmol) of cyclooctylamine and 0.1 g of dry LiCl are added under inert atmosphere to 70 ml of dry NMP and 15 ml of dry pyridine and cooled to 5° C. Then, 2.39 g (9 mmol) of 1,3,5-benzenetricarboxylic acid trichloride are added. The reaction mixture is heated to 75° C. and stirred. After 2 hours the reaction mixture is added to 300 ml of ice water. Customary work-up (recrystallization from N,N-dimethylformamide) gives 1,3,5-benzenetricarboxylic acid tris(cyclooctylamide).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US07423088B2 |
|---|
| 출처 데이터셋 | uspto-grants-2008_09 |
|---|
| ORD ID | ord-0249888884cf4a97b3e2384f1b38319c |
|---|
| 출처 메모 | uspto-grants-2008_09 |
|---|
