Ethyl phosphorochloridite → Diethyl 2-[bis(3,5-di-t-butyl-4-methoxyphenyl)phosphino]phenylphosphonite

HRID 309662

반응식

[C:1]([CH3:2])([CH3:3])([CH3:4])[c:5]1[cH:6][c:7]([P:17]([c:18]2[c:19]([Br:24])[cH:20][cH:21][cH:22][cH:23]2)[c:25]2[cH:26][c:27]([C:37]([CH3:38])([CH3:39])[CH3:40])[c:28]([O:35][CH3:36])[c:29]([C:31]([CH3:32])([CH3:33])[CH3:34])[cH:30]2)[cH:8][c:9]([C:13]([CH3:14])([CH3:15])[CH3:16])[c:10]1[O:11][CH3:12].[CH2:49]([Li:50])[CH2:51][CH2:52][CH3:53].[Cl:41][P:42]([O:43][CH2:44][CH3:45])[O:46][CH2:47][CH3:48]>>[C:1]([CH3:2])([CH3:3])([CH3:4])[c:5]1[cH:6][c:7]([P:17]([c:18]2[c:19]([P:42]([O:43][CH2:44][CH3:45])[O:46][CH2:47][CH3:48])[cH:20][cH:21][cH:22][cH:23]2)[c:25]2[cH:26][c:27]([C:37]([CH3:38])([CH3:39])[CH3:40])[c:28]([O:35][CH3:36])[c:29]([C:31]([CH3:32])([CH3:33])[CH3:34])[cH:30]2)[cH:8][c:9]([C:13]([CH3:14])([CH3:15])[CH3:16])[c:10]1[O:11][CH3:12]

참가 물질

반응물 3

HCID 68530Ethyl phosphorochloridite

HCID 12115810Bis(3,5-di-t-butyl-4-methoxyphenyl)(2-bromophenyl)phosphine

HCID 178418339Butyllithium

생성물 1

HCID 12115811Diethyl 2-[bis(3,5-di-t-butyl-4-methoxyphenyl)phosphino]phenylphosphonite

출처 및 근거

ORD 기록: ord-a705332bfac5411e99416e87c6c72064
출처 데이터셋: Training data from https://doi.org/10.1039/C8SC04228D (8/10)
DOI: 10.1039/C8SC04228D

연결된 노트

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