Ethyl ketone → (2,2-Diethyl-1,3-dioxan-5-yl)methanol

반응식

[OH:1][CH2:2][CH:3]([CH2:6][OH:7])[CH2:4][OH:5].[CH3:8][CH2:9][C:10](=O)[CH2:11][CH3:12]>>[CH2:9]([C:10]1([CH2:11][CH3:12])[O:5][CH2:4][CH:3]([CH2:6][OH:7])[CH2:2][O:1]1)[CH3:8]

참가 물질

반응물 2

HCID 7288Ethyl ketone

HCID 78432Trimethylolmethane

생성물 1

HCID 14629254(2,2-Diethyl-1,3-dioxan-5-yl)methanol수율 46%

실험 절차

The same procedure as in the step (7a) of Example 7 was repeated using 2-(hydroxymethyl)-1,3-propanediol, and 3-pentanone to obtain the title compound (1.5 g, yield: 46%) as a light yellow oil.

출처 및 근거

ORD 기록: ord-df690b281915412e85a8cfc989c8363c
출처 데이터셋: uspto-grants-2008_09
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07425634B2

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