참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Trimethoxysilane | HCID 17215 | — |
| 반응물 | 1,2-Epoxy-5-hexene | HCID 66314 | — |
| 촉매 | Chlorotris(triphenylphosphine)rhodium(I) | HCID 84599 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | 5,6-Epoxyhexyltrimethoxysilane | HCID 10198352 | 61% |
반응 단계
In a 100 mL round-bottom flask were placed 8.5 mL of 5,6-epoxy-1-hexene (0.1 moles), 1.5 equivalents of trimethoxysilane (17 mL), 30 mL of toluene dried by refluxing with sodium benzophenone ketyl, and 3 mg of tris(triphenylphosphine)rhodium (I) chloride. The resulting light purple solution was stirred and heated at 80° C. for 12 hours. The solvent was removed under reduced pressure, and the resulting oil subjected to fractional vacuum distillation. 5,6-Epoxyhexyltrimethoxysilane was obtained (13.5 g, 61% yield) as a colorless liquid.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US06210790B1 |
|---|
| 출처 데이터셋 | uspto-grants-2001_04 |
|---|
| ORD ID | ord-f5b42606a5144da88150f33ffc142887 |
|---|
| 출처 메모 | uspto-grants-2001_04 |
|---|
