Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Allyl bromide → Phenyl-ferrocenyl-butadien
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Allyl bromide | HCID 7841 | — |
| 반응물 | 1,2-Diiodoethane | HCID 12224 | — |
| 반응물 | Samarium | HCID 23951 | — |
| 반응물 | Cyclopenta-1,3-diene;cyclopenta-2,4-dien-1-yl(phenyl)methanone;iron(2+) | HCID 176468997 | — |
| 반응물 | HCID 178506586 | HCID 178506586 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | Phenyl-ferrocenyl-butadien | HCID 129629832 | 99% |
반응 단계
In a nitrogen environment, about 330 mg (2.20 mmole) of samarium and about 500 mg (1.77 mmole) of 1,2-diiodoethane is disposed in a round-bottomed flask. About 20 ml of tetrahydrofuran is added into the round-bottomed flask. The mixture in the round-bottomed flask is stirred until a deep-blue samarium diiodide solution is obtained. Following the process flow described in Example 1, about 348 mg (1.20 mmole) of benzoylferrocene reacts with about 242 mg (2.0 mmole) of allyl bromide to produce oil-type 1-Ferrocenyl-1-phenyl-1,3-butadiene (3c) with a weight of about 373 mg (1.19 mmole) and a yield of about 99%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06211392B1 |
| 출처 데이터셋 | uspto-grants-2001_04 |
| ORD ID | ord-bbdbdb3bbb01451496fa2ee7abb17493 |
| 출처 메모 | uspto-grants-2001_04 |