(1,1'-Biphenyl)-2,3'-diol → LG190155

HRID 324603

반응식

[CH3:1][C:2]1[CH:3]=[C:4]([C:16]2([C:22]3[CH:27]=[CH:26][C:25]([O:28][CH2:29][C:30](=[O:35])[C:31]([CH3:34])([CH3:33])[CH3:32])=[C:24]([CH3:36])[CH:23]=3)[CH2:21][CH2:20]C[CH2:18][CH2:17]2)[CH:5]=[CH:6][C:7]=1[O:8][CH2:9][C:10](=[O:15])[C:11]([CH3:14])([CH3:13])[CH3:12].C1C=C(C2C=CC=C(O)C=2)C(O)=CC=1>>[CH3:36][C:24]1[CH:23]=[C:22]([C:16]([C:4]2[CH:5]=[CH:6][C:7]([O:8][CH2:9][C:10](=[O:15])[C:11]([CH3:14])([CH3:13])[CH3:12])=[C:2]([CH3:1])[CH:3]=2)([CH2:17][CH3:18])[CH2:21][CH3:20])[CH:27]=[CH:26][C:25]=1[O:28][CH2:29][C:30](=[O:35])[C:31]([CH3:32])([CH3:33])[CH3:34]

참가 물질

반응물 2

HCID 33665(1,1'-Biphenyl)-2,3'-diol

HCID 9891850LG190119

생성물 1

HCID 15521394LG190155

실험 절차

Compound 7 was prepared analogously to Compound 4 except that the compound of Example 3 (6) was used instead of the compound of Example 1 (3). 1HNMR (CDCl3) δ: 6.89 (m, 4 H, Ar—H), 6.49 (d, J=8.3 Hz, 2 H, Ar—H), 4.82 (s, 4 H, CH2O), 2.23 (s, 6 H, Ar—CH3), 2.00 (q, J=7.3 Hz, 4 H, CH2CH3), 1.23 (s, 18 H, t-Bu), 0.58 (t, J=7.3 Hz, 6 H, CH2CH3).

출처 및 근거

ORD 기록: ord-1caaa62b36a14804a8b2dbdbec3d9ca2
출처 데이터셋: uspto-grants-2001_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06218430B1

연결된 노트

불러오는 중…