Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
2-Acetylnaphthalene → (S)-(-)-1-(2-Naphthyl)ethanol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 2-Acetylnaphthalene | HCID 7122 | — |
| 반응물 | alpha-Methylnaphthalene-2-methanol | HCID 98243 | — |
| 반응물 | (R)-(+)-1-(2-Naphthyl)ethanol | HCID 6976569 | — |
| 생성물 | (S)-(-)-1-(2-Naphthyl)ethanol | HCID 6976568 | 50% |
반응 단계
As shown here, the biochemical conversion reaction of immobilized green pea protein for the substrate 1-(2-naphthyl)ethanol (201 mg) requires 4 days by going through bioconversion to 2-acetonaphthone accompanying sterically selective oxidation of (R)-1-(2-naphthyl)ethanol to obtain 100 mg of (S)-1-(2-naphthyl)ethanol at a yield of 50% at an optical purity of 99% e.e. or higher (see FIG. 1).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06218581B1 |
| 출처 데이터셋 | uspto-grants-2001_04 |
| ORD ID | ord-7b35a6765154448fa7d62659ae817dc6 |
| 출처 메모 | uspto-grants-2001_04 |