Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzoyl chloride → Benzoyl fluoride
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzoyl chloride | HCID 7412 | — |
| 반응물 | (Bis(2-methoxyethyl)amino)sulfur trifluoride | HCID 2734690 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | Benzoyl fluoride | HCID 67999 | 99.9% |
반응 단계
A solution of benzoyl chloride (141 mg, 1 mmol) in CH2Cl2 (5.0 mL) was added to bis(methoxyethyl)aminosulfur trifluoride (567 mg, 3.0 mmol ) under N2 and stirred for 16 h at room temperature. After work-up as above benzoyl fluoride (124 mg, quantitative yield) was obtained. The product was identified by g.c.m.s. M+=124
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06222064B1 |
| 출처 데이터셋 | uspto-grants-2001_04 |
| ORD ID | ord-c698cb0ddf45485f8c3f34cce99c38f2 |
| 출처 메모 | uspto-grants-2001_04 |