Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Glycidyl methacrylate → 3-(Methacryloyloxy)-2-hydroxypropyl methyl-5-carbomethoxybicyclo-[2.2.1]hept-2-ene-6-carboxylate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Glycidyl methacrylate | HCID 7837 | — |
| 반응물 | 2,6-Di-tert-butyl-4-methylphenol | HCID 31404 | — |
| 반응물 | Methyl-5-carbomethoxybicyclo [2.2.1]hept-2-ene-6-carboxylic acid | HCID 54301392 | — |
| 촉매 | Tetramethylammonium chloride | HCID 6379 | — |
| 생성물 | 3-(Methacryloyloxy)-2-hydroxypropyl methyl-5-carbomethoxybicyclo-[2.2.1]hept-2-ene-6-carboxylate | HCID 20464889 | — |
반응 단계
This acid ester (50 g) was heated with glycidyl methacrylate (40 g) at 100° C. in the presence of 0.27 g of tetramethylammonium chloride and 0.13 g of 2,6-di-tert.butyl-p-cresol until the epoxide content had fallen to a negligible level; the desired ester so formed was a viscous liquid.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04440850 |
| 출처 데이터셋 | uspto-grants-1984_04 |
| ORD ID | ord-5a7f171be5fc4b768eb0eb9d95b8dd57 |
| 출처 메모 | uspto-grants-1984_04 |