1-Bromopentadecane → 3-Pentadecylthiopropanol

반응식

Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].[SH:17][CH2:18][CH2:19][C:20](OCC)=[O:21].[H-].[Al+3].[Li+].[H-].[H-].[H-]>>[CH2:2]([S:17][CH2:18][CH2:19][CH2:20][OH:21])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]

참가 물질

반응물 3

HCID 123941-Bromopentadecane

HCID 21625Ethyl 3-mercaptopropionate

HCID 21226445Aluminium lithium hydride

생성물 1

HCID 204620623-Pentadecylthiopropanol수율 84%

실험 절차

1-Bromopentadecane is reacted in the usual way with ethyl β-mercaptopropionate and the syrup obtained reduced with lithium aluminium hydride to give a yield of 84% of theory of 3-pentadecylthiopropanol; m.p. 36°-39° C.

후처리

customthe syrup obtained

출처 및 근거

ORD 기록: ord-b31fba29f7574ee6a1a36ee713ddad8d
출처 데이터셋: uspto-grants-1984_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04444766

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