Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzoic Acid → 2-Chloro-5-cyclopropylmethanesulfonyl-benzoic acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzoic Acid | HCID 243 | — |
| 반응물 | Iodine | HCID 807 | — |
| 반응물 | Bromomethylcyclopropane | HCID 81503 | — |
| 반응물 | 2-Chloro-5-sulfino-benzoic acid | HCID 15112904 | — |
| 용매 | Cyclopropanemethanol | HCID 75644 | — |
| 생성물 | 2-Chloro-5-cyclopropylmethanesulfonyl-benzoic acid | HCID 43560564 | 8% |
반응 단계
The title compound was synthesised according to the procedure described for the synthesis of 2-Chloro-5-methanesulfonyl)-benzoic acid from 2-Chloro-5-sulfino-benzoic acid and Bromomethyl-cyclopropane (+catalytic amount I2) in 20 ml cyclopropyl methanol/20 ml water and obtained in 8% yield. MS (m/e): 273.1 (MH−, 100%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07427612B2 |
| 출처 데이터셋 | uspto-grants-2008_09 |
| ORD ID | ord-6074aae533fb4a4fa4fccb4f830f50df |
| 출처 메모 | uspto-grants-2008_09 |