참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | N-bromobutanimide | HCID 67184 | — |
| 반응물 | 4'-Methyl-2-nitro-1,1'-biphenyl | HCID 10443194 | — |
| 촉매 | Azobisisobutyronitrile | HCID 6547 | — |
| 용매 | Carbon Tetrachloride | HCID 5943 | — |
| 생성물 | 1,1'-Biphenyl, 4'-(bromomethyl)-2-nitro- | HCID 11779072 | 101.2% |
반응 단계
A mixture containing 6.5 g of 4-methyl-2'-nitrobiphenyl, 5.42 g of NBS, 118 mg of azo-bis-isobutyronitrile and 500 ml of carbon tetrachloride is refluxed for 5 hours. It is cooled to 0° C. and filtered and the filtrate is concentrated to give 9 g of an oily product, which is used as such in the next step.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US05270317 |
|---|
| 출처 데이터셋 | uspto-grants-1993_12 |
|---|
| ORD ID | ord-24278e22323e4ebf969f711e19fec804 |
|---|
| 출처 메모 | uspto-grants-1993_12 |
|---|
