Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Dimethylformamide → Acrylic Acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Dimethylformamide | HCID 6228 | — |
| 반응물 | 4-(1-Methylpropoxy)phenyl 4-(12-bromododecyloxy)benzoate | HCID 19734059 | — |
| 생성물 | Acrylic Acid | HCID 6581 | — |
| 생성물 | Tetramethylammonium hydroxide | HCID 60966 | — |
반응 단계
A solution of 6 mmol (3.2 g) of the bromo compound obtained in (2), 10 mmol (0.72 g) of acrylic acid, and 10 mmol (1.8 g) of tetramethylammonium hydroxide (pentahydrate) in 30 ml of DMF was stirred for 10 hours at room temperature. To the resulting reaction solution was added water and then extracted with ether. The extract was concentrated, and the concentrate was purified by column chromatography to obtain 2.2 g of the objective monomer (3b). (Yield: 71%)
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05271866 |
| 출처 데이터셋 | uspto-grants-1993_12 |
| ORD ID | ord-b7348a1330274d1c8b19a7da8498f468 |
| 출처 메모 | uspto-grants-1993_12 |