Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
(4S,5S)-4,5-bis(3'-benzyloxy-4'-methoxyphenyl)-2-oxo-1,3,2-dioxathiolane → (4S,5S)-4,5-bis(3'-Benzyloxy-4'-methoxyphenyl)-2,2-dioxo-1,3,2-dioxathiolane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | (4S,5S)-4,5-bis(3'-benzyloxy-4'-methoxyphenyl)-2-oxo-1,3,2-dioxathiolane | HCID 11071547 | — |
| 반응물 | Sodium periodate | HCID 23667635 | — |
| 촉매 | Ruthenium trichloride hydrate | HCID 6093376 | — |
| 용매 | Acetonitrile methylene chloride | HCID 21877088 | — |
| 생성물 | (4S,5S)-4,5-bis(3'-Benzyloxy-4'-methoxyphenyl)-2,2-dioxo-1,3,2-dioxathiolane | HCID 14831925 | — |
반응 단계
Mixture: 33 g (63 mmol) of (4S,5S)-4,5-bis(3'-benzyloxy-4'-methoxyphenyl)-2-oxo-1,3,2-dioxathiolane, 300 ml of dichloromethane/acetonitrile 1:1, 200 ml of ice-water, 72.7 mg (0.35 mmol) of ruthenium (III) chloride hydrate, 26.83 g (125.4 mmol) of sodium metaperiodate.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05272270 |
| 출처 데이터셋 | uspto-grants-1993_12 |
| ORD ID | ord-b4a3d2909ebf40e0bcccdff06fb959c6 |
| 출처 메모 | uspto-grants-1993_12 |