Water → Trans-phenylpropylene oxide

HRID 327853

반응식

HRID 327853 반응식
[CH3:1]/[CH:2]=[CH:3]/[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.[OH2:10]>>[CH:3](=[O:10])[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.[C:4]1([CH:3]2[O:10][CH:2]2[CH3:1])[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1

참가 물질

4

반응물 2

HCID 962WaterHCID 252325trans-beta-METHYLSTYRENE

생성물 2

HCID 240Benzaldehyde수율 14%HCID 123339Trans-phenylpropylene oxide수율 86%

실험 절차

The metal-catalyzed epoxidation of trans-β-methylstyrene was performed as described in Example 2 with the substitution of Co(OAc)2. 4 H2O (where OAc=acetate) (0.0058 g, 2.3×10-5 moles) as the catalyst. After 16 hours of reaction, the complete oxidation of the substrate produced benzaldehyde (14%) and 1-phenylpropylene oxide (86%).

후처리

  1. customAfter 16 hours of reaction

출처 및 근거

ORD 기록
ord-1124b1086ea74b099e9de1b9985c1c60
출처 데이터셋
uspto-grants-1993_12
특허 번호
US05274139

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