3-[2-[[5-[(Methylsulfonyl)oxy]pentyl]oxy]phenyl]-2-propenoic acid methyl ester → HCID 86747452, 화합물

반응식

[CH3:1][O:2][C:3](=[O:19])/C=C/C1C=CC=CC=1OCCCCCO.COC(=O)[CH:23]=[CH:24][C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][C:26]=1[O:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][O:37][S:38]([CH3:41])(=[O:40])=[O:39]>>[CH3:1][O:2][C:3](=[O:19])[C:24]([C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][C:26]=1[O:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][O:37][S:38]([CH3:41])(=[O:39])=[O:40])=[CH2:23]

참가 물질

반응물 2

HCID 537153333-[2-[[5-[(Methylsulfonyl)oxy]pentyl]oxy]phenyl]-2-propenoic acid methyl ester

HCID 67780416HCID 67780416, 화합물

생성물 1

HCID 86747452HCID 86747452, 화합물

실험 절차

Using the procedure of example 32, 1.09 g (4.13 mmol) of (E)-3-[2-[(5-hydroxypentyl)oxy]phenyl]-2-propenoic acid methyl ester was converted into 1.37 g (97%) of (E)-(3-[2-[[5-[(methylsulfonyl)oxy]pentyl]oxy]phenyl]-2-propenoic acid methyl ester, as a yellow oil.

출처 및 근거

ORD 기록: ord-526e5df08b984251b6a1aa7e28159301
출처 데이터셋: uspto-grants-1993_12
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05273999

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