Tetradec-2-ene → 1-Tricosene

반응식

[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH:9]=[CH:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21].[CH3:22][CH2:23]CCCCCCC=CCCCCCCCC.CC=CCCCCCCCCCCCCC.CC=CCCCCCCCCCCC>>[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23].[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21]

참가 물질

반응물 4

HCID 33650Tetradec-2-ene

HCID 521661CID 521661

HCID 5250202-Hexadecene

HCID 4460170cis-9-Heneicosene

생성물 2

HCID 1811541-Tricosene

HCID 3015374Heneicosene

실험 절차

A mixture of 9-triscosene and 9-heneicosene was prepared by following the process described in Example 8, namely by conducting, over 39 g. of the aforedescribed rehenium-containing catalyst, at 60° C., a mixture of 196 g. (0.79 mole) of 9-octadecene, 58 g. (0.26 mole) of 2-hexadecene, and 16 g. (0.08 mole) of 2-tetradecene. After a reaction time of 5 hours and with a throughput of 200 ml. of olefin mixture per hour, 3.2% by weight of tricosene and 1.4% by weight of heneicosene were obtained. The content of the cis-isomer was 24%.