Sodium Methoxide → 4-Methoxy[1]benzothieno[3,2-d][1,2,3]triazine

HRID 328674노트

반응식

HRID 328674 반응식
Cl[C:2]1[C:3]2[S:10][C:9]3[CH:11]=[CH:12][CH:13]=[CH:14][C:8]=3[C:4]=2[N:5]=[N:6][N:7]=1.[CH3:15][O-:16].[Na+]>CO>[CH3:15][O:16][C:2]1[C:3]2[S:10][C:9]3[CH:11]=[CH:12][CH:13]=[CH:14][C:8]=3[C:4]=2[N:5]=[N:6][N:7]=1

참가 물질

4

반응물 2

HCID 10942334Sodium MethoxideHCID 12269873HCID 12269873, 화합물

생성물 1

HCID 3234304-Methoxy[1]benzothieno[3,2-d][1,2,3]triazine

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

A 2.2 g. portion of the product of Example 1 was stirred at reflux temperature in 100 ml. of methanol with 0.7 g. of sodium methoxide for one hour. When the reaction mixture was cooled, the product, 1.9 g. of 4-methoxy[1]-benzothieno[3,2-d]-v-triazine, m.p. 165°-167° C., crystallized and needed no further purification.

후처리

  1. temperatureat reflux temperature in 100 ml
  2. temperatureWhen the reaction mixture was cooled
  3. customof 4-methoxy[1]-benzothieno[3,2-d]-v-triazine, m.p. 165°-167° C., crystallized
  4. customno further purification

출처 및 근거

ORD 기록
ord-41716bf0ef4347d887d34487b671ca35
출처 데이터셋
uspto-grants-1977_04
특허 번호
US04018768

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