Benzyl Bromide → Benzenemethanamine, N,N-diethyl-

HRID 329658

반응식

HRID 329658 반응식
[CH2:1](Br)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH2:9]([NH:11][CH2:12][CH3:13])[CH3:10]>CCOCC>[CH2:9]([N:11]([CH2:12][CH3:13])[CH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)[CH3:10]

참가 물질

4

반응물 2

HCID 7498Benzyl BromideHCID 8021Diethylamine

생성물 1

HCID 61211Benzenemethanamine, N,N-diethyl-

시약·촉매·용매 1

HCID 3283Diethyl Ether용매2회

실험 절차

A mixture of 11.9 ml of benzyl bromide in 100 ml of ether was added dropwise to a mixture of 30.9 ml of diethylamine in 100 ml of ether. This mixture was stirred overnight then filtered and washed with ether. The combined filtrate and wash was washed with water, dried and concentrated to an oil. This oil was distilled through a Kugelrohr and the fraction boiling at <70° C., 1.5 mm collected, giving 10.6 g of N,N-diethylbenzenemethanamine as an oil.

후처리

  1. filtrationthen filtered
  2. washwashed with ether
  3. washThe combined filtrate and wash
  4. washwas washed with water
  5. customdried
  6. concentrationconcentrated to an oil
  7. distillationThis oil was distilled through a Kugelrohr
  8. customthe fraction boiling at <70° C., 1.5 mm collected

출처 및 근거

ORD 기록
ord-c99b104171c84824b229bcb5f824dde4
출처 데이터셋
uspto-grants-1990_01
특허 번호
US04892885

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