5-Hydroxymethyl-3-furancarboxylic acid ethyl ester → Ethyl 5-formylfuran-3-carboxylate
반응식
[CH2:1]([O:3][C:4]([C:6]1[CH:10]=[C:9]([CH2:11][OH:12])[O:8][CH:7]=1)=[O:5])[CH3:2]>ClCCl.[O-2].[O-2].[Mn+4]>[CH2:1]([O:3][C:4]([C:6]1[CH:10]=[C:9]([CH:11]=[O:12])[O:8][CH:7]=1)=[O:5])[CH3:2]참가 물질
4
실험 절차
5-Hydroxymethyl-3-furancarboxylic acid ethyl ester (0.34 g, 2.0 mmol) was dissolved in dichloromethane (20 mL), manganese dioxide (1.4 g, 15.9 mmol) was added, and the mixture was stirred overnight. The reaction mixture was filtered through celite, and the solvent was evaporated under reduced pressure to give the title compound (0.26 g).
후처리
- filtrationThe reaction mixture was filtered through celite
- customthe solvent was evaporated under reduced pressure
출처 및 근거
- ORD 기록
- ord-a5af19dec599455f9b009cffcde12477
- 출처 데이터셋
- uspto-grants-2014_11
- 특허 번호
- US08877805B2
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