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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 333563생성일: 2026년 10월 23일

Methacrylic Acid → Benzyl methacrylate methacrylic acid 2-hydroxyethyl methacrylate

https://huagongshe.com/ko/reaction/333563

반응식

참여 물질

역할이름HCID투입량
반응물Methacrylic AcidHCID 4093—
반응물4-MethoxyphenolHCID 9015—
반응물2-Hydroxyethyl MethacrylateHCID 13360—
반응물Benzyl methacrylateHCID 17236—
용매Propylene glycol methyl ether acetateHCID 7946—
생성물Benzyl methacrylate methacrylic acid 2-hydroxyethyl methacrylateHCID 69230823—

반응 조건

온도80 °C

반응 단계

Specifically, 53.0 g (0.300 mol) of benzyl methacrylate, 11.7 g (0.090 mol) of 2-hydroxyethyl methacrylate, 7.92 g (0.110 mol) of methacrylic acid, and 50 g of propylene glycol monomethylether acetate were placed in a 300-ml four-necked flask and stirred at 80° C. under a nitrogen atmosphere. A solution prepared by dissolving 0.3118 g (1.91×10−3 mol) of a thermal polymerization initiator (2,2′-azobisisobutylnitrile (AIBN) in 10 g of propylene glycol monomethylether acetate) was added thereto, and stirred for 6 hours. Subsequently, the supply of nitrogen was stopped, and a solution of 0.22 g (1.5×10−3 mol) of p-methoxyphenol dissolved in 15 g of propylene glycol monomethylether acetate was added thereto, and the temperature was elevated to 95° C. and stirred for 2 hours. A binder (benzyl methacrylate/methacrylic acid/2-hydroxyethyl methacrylate copolymer) was thus obtained. The resulting binder had an acid value of 30 mgKOH/g and a weight average molecular weight of 15,000.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US08883378B2
출처 데이터셋uspto-grants-2014_11
ORD IDord-e190864669e04e9e96f8f11279dff499
출처 메모uspto-grants-2014_11