참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Methacrylic Acid | HCID 4093 | — |
| 반응물 | 4-Methoxyphenol | HCID 9015 | — |
| 반응물 | 2-Hydroxyethyl Methacrylate | HCID 13360 | — |
| 반응물 | Benzyl methacrylate | HCID 17236 | — |
| 용매 | Propylene glycol methyl ether acetate | HCID 7946 | — |
| 생성물 | Benzyl methacrylate methacrylic acid 2-hydroxyethyl methacrylate | HCID 69230823 | — |
반응 단계
Specifically, 53.0 g (0.300 mol) of benzyl methacrylate, 11.7 g (0.090 mol) of 2-hydroxyethyl methacrylate, 7.92 g (0.110 mol) of methacrylic acid, and 50 g of propylene glycol monomethylether acetate were placed in a 300-ml four-necked flask and stirred at 80° C. under a nitrogen atmosphere. A solution prepared by dissolving 0.3118 g (1.91×10−3 mol) of a thermal polymerization initiator (2,2′-azobisisobutylnitrile (AIBN) in 10 g of propylene glycol monomethylether acetate) was added thereto, and stirred for 6 hours. Subsequently, the supply of nitrogen was stopped, and a solution of 0.22 g (1.5×10−3 mol) of p-methoxyphenol dissolved in 15 g of propylene glycol monomethylether acetate was added thereto, and the temperature was elevated to 95° C. and stirred for 2 hours. A binder (benzyl methacrylate/methacrylic acid/2-hydroxyethyl methacrylate copolymer) was thus obtained. The resulting binder had an acid value of 30 mgKOH/g and a weight average molecular weight of 15,000.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US08883378B2 |
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| 출처 데이터셋 | uspto-grants-2014_11 |
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| ORD ID | ord-e190864669e04e9e96f8f11279dff499 |
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| 출처 메모 | uspto-grants-2014_11 |
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