Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Triphenylstannane → HCID 11152734, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Triphenylstannane | HCID 6460 | — |
| 반응물 | O-Xylene | HCID 7237 | — |
| 반응물 | HCID 178466770 | HCID 178466770 | — |
| 용매 | Acetonitrile | HCID 6342 | — |
| 생성물 | HCID 11152734 | HCID 11152734 | — |
반응 단계
In a nitrogen atmosphere, 2-(4-acetyl-phenylazo)-2-(3,3-dimethyl-3,4-dihydro-2H-isoquinoline-1-ylidene)-acetamide (Asinex Corp., Russia) is dissolved in acetonitrile, and the obtained product is added with xylene in which triphenyl tin hydride (Aldrich, Corp., USA) is dissolved, and the mixture is refluxed. The refluxed product is cooled to room temperature and an insoluble matter is separated by filtration. The solvent is removed from the filtrate by reducing the pressure. The residue containing the reaction product is purified by column chromatography to obtain the title compound.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08883504B2 |
| 출처 데이터셋 | uspto-grants-2014_11 |
| ORD ID | ord-ce31b888ce6146548f9a61256b784f0d |
| 출처 메모 | uspto-grants-2014_11 |