4-Methylpyridine → Ethyl 2-furoate

HRID 337548

반응식

CC1C=CN=CC=1.N1C=CC([C:14]2[CH:18]=[CH:17][O:16][C:15]=2[C:19]([O:21][CH2:22][CH3:23])=[O:20])=CC=1>>[O:16]1[CH:17]=[CH:18][CH:14]=[C:15]1[C:19]([O:21][CH2:22][CH3:23])=[O:20]

참가 물질

반응물 2

HCID 79634-Methylpyridine

HCID 23144513Ethyl 3-(4-pyridyl)furan-2-carboxylate

생성물 1

HCID 11980Ethyl 2-furoate

실험 절차

In a manner similar to that in Reference Example 13, by using 4-methylpyridine in place of 3,4-dimethylpyridine and using ethyl 3-(4-pyridyl)furan-2-carboxylate (133 mg, 0.612 mmol) obtained in Step 1, in place of ethyl furan-2-carboxylate, the entitled Compound ad (35.3 mg, 18%) was obtained.

출처 및 근거

ORD 기록: ord-0a9cf6d669a9439d8ae342e165398303
출처 데이터셋: uspto-grants-2014_11
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08889718B2

연결된 노트

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