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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 341727생성일: 2026년 10월 27일

Methanol → Trimethylsilylmethyl acrylate t-butyl methacrylate

https://huagongshe.com/reaction/341727

반응식

참여 물질

역할이름HCID투입량
반응물MethanolHCID 887—
반응물AzobisisobutyronitrileHCID 6547—
반응물tert-Butyl methacrylateHCID 11448—
반응물(Trimethylsilyl)methyl prop-2-enoateHCID 15374992—
용매WaterHCID 962—
용매TolueneHCID 1140—
생성물Trimethylsilylmethyl acrylate t-butyl methacrylateHCID 8675351585%

반응 단계

t-butyl methacrylate and trimethylsilylmethyl acrylate were mixed at a mixing ratio of 1:1 so as to form a toluene solution having a monomer concentration of 5 mol/liter. Next, 2 mol %, on the basis of the monomer, of AIBN was added to the mixture, and the mixture was retained in an oil bath at 80° C. for 3 hours with stirring. Thereafter, the mixture was left standing at room temperature to cool, and the reaction product was diluted with toluene. The toluene solution was dropped into large quantities of a mixed solvent of methanol and water having a mixing ratio of 1:1, and the resulting precipitate was filtered and dried to obtain a trimethylsilylmethyl acrylate/t-butyl methacrylate copolymer represented by the following formula, at a yield of 85%. The molecular weight was 23,000 and the dispersion was 1.63. ##STR17## wherein each of m and n is a positive integer.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US05856071
출처 데이터셋uspto-grants-1999_01
ORD IDord-af602660fb2a4c7e935157c6cd9ed329
출처 메모uspto-grants-1999_01