참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Hydrogen Peroxide | HCID 784 | — |
| 반응물 | Acrylamide | HCID 6579 | — |
| 반응물 | Acrylic Acid | HCID 6581 | — |
| 반응물 | Potassium Hydroxide | HCID 14797 | — |
| 반응물 | Sodium Persulfate | HCID 62655 | — |
| 반응물 | 2,2'-Azobis(2-methylpropanimidamide) dihydrochloride | HCID 76344 | — |
| 반응물 | L-Ascorbic Acid | HCID 54670067 | — |
| 용매 | Water | HCID 962 | — |
| 용매 | Methylene-bisacrylamide | HCID 53800990 | — |
| 생성물 | Potassium;prop-2-enamide;prop-2-enoate | HCID 16212816 | — |
반응 단계
In a polymerization vessel, 0.9 g methylene bisacrylamide and 192 g acrylamide were dissolved in 500 g water first and mixed with 84 g acrylic acid. Then, the monomer solution was neutralized with 102 g potassium hydroxide solution (45%), cooled to 10° C. and blown out with nitrogen. After addition of the catalyst solutions (1.6 g sodium peroxidisulfate, 0.2 g hydrogen peroxide (35%) and 0.01 g ascorbic acid) and 10 g 2,2'-azobis(2-methyl-propionamidine)dihydrochloride used as blowing agent, the polymerization was initiated. Thorough mixing of the catalyst solutions with the monomer solution is a precondition for a homogeneous polymerization in the whole polymer block. The maximum temperature of 100° C. (in a well-insulated polymerization vessel) was reached within 10 minutes. After completed polymerization, the polymer gel was crumbled, dried at 120° C. and ground to the desired size fraction. A cross-linked potassium acrylate/acrylamide copolymer was obtained which had a porous structure resulting from the entrapped nitrogen bubbles.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US05856370 |
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| 출처 데이터셋 | uspto-grants-1999_01 |
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| ORD ID | ord-8654cac7ef3c41a787072ecf54b1fec3 |
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| 출처 메모 | uspto-grants-1999_01 |
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