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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 341873생성일: 2026년 10월 26일

Hydrogen Peroxide → Potassium;prop-2-enamide;prop-2-enoate

https://huagongshe.com/reaction/341873

반응식

참여 물질

역할이름HCID투입량
반응물Hydrogen PeroxideHCID 784—
반응물AcrylamideHCID 6579—
반응물Acrylic AcidHCID 6581—
반응물Potassium HydroxideHCID 14797—
반응물Sodium PersulfateHCID 62655—
반응물2,2'-Azobis(2-methylpropanimidamide) dihydrochlorideHCID 76344—
반응물L-Ascorbic AcidHCID 54670067—
용매WaterHCID 962—
용매Methylene-bisacrylamideHCID 53800990—
생성물Potassium;prop-2-enamide;prop-2-enoateHCID 16212816—

반응 조건

온도10 °C

반응 단계

In a polymerization vessel, 0.9 g methylene bisacrylamide and 192 g acrylamide were dissolved in 500 g water first and mixed with 84 g acrylic acid. Then, the monomer solution was neutralized with 102 g potassium hydroxide solution (45%), cooled to 10° C. and blown out with nitrogen. After addition of the catalyst solutions (1.6 g sodium peroxidisulfate, 0.2 g hydrogen peroxide (35%) and 0.01 g ascorbic acid) and 10 g 2,2'-azobis(2-methyl-propionamidine)dihydrochloride used as blowing agent, the polymerization was initiated. Thorough mixing of the catalyst solutions with the monomer solution is a precondition for a homogeneous polymerization in the whole polymer block. The maximum temperature of 100° C. (in a well-insulated polymerization vessel) was reached within 10 minutes. After completed polymerization, the polymer gel was crumbled, dried at 120° C. and ground to the desired size fraction. A cross-linked potassium acrylate/acrylamide copolymer was obtained which had a porous structure resulting from the entrapped nitrogen bubbles.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US05856370
출처 데이터셋uspto-grants-1999_01
ORD IDord-8654cac7ef3c41a787072ecf54b1fec3
출처 메모uspto-grants-1999_01