Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1,3-Dichloro-1,1,2,2,3-pentafluoropropane → 1,3-Dichloro-1,1,2,2,3-pentafluoropropane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1,3-Dichloro-1,1,2,2,3-pentafluoropropane | HCID 62353 | — |
| 반응물 | HCID 178418361 | HCID 178418361 | — |
| 생성물 | 1,3-Dichloro-1,1,2,2,3-pentafluoropropane | HCID 62353 | — |
| 생성물 | 1,1,2,2,3-Pentafluoropropane | HCID 69624 | — |
반응 단계
HCFC-225cb was reduced using the reactor and procedures of Example 2 except that the catalyst was prepared from 0.5% Pd/alumina mixed with 50 cc glass helices. The organics flow rate was 4 cc/hr. with a hydrogen flow rate of 90±10 cc/min. The temperature was maintained at 190°±3° C. for 144 hours. HFC-245ca in an 87-92% selectivity and greater than 98% conversion of HCFC-225cb resulted. As the data from Example 4, shown on Table I below indicate, the Pd/alumina catalyst is stable for 144 hours towards the reduction of HCFC-225cb to HFC-245ca.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05856594 |
| 출처 데이터셋 | uspto-grants-1999_01 |
| ORD ID | ord-74d297141d5e4b69b91db61bd8e9dde3 |
| 출처 메모 | uspto-grants-1999_01 |