1,10-Phenanthroline → Copper Bis(1,10-phenanthroline) Sulfate

HRID 342364

반응식

HRID 342364 반응식
[S:1]([O-:5])([O-:4])(=[O:3])=[O:2].[Cu+2:6].O.[N:8]1[C:21]2[C:12](=[CH:13][CH:14]=[C:15]3[C:20]=2[N:19]=[CH:18][CH:17]=[CH:16]3)[CH:11]=[CH:10][CH:9]=1.[N:22]1[C:35]2[C:26](=[CH:27][CH:28]=[C:29]3[C:34]=2[N:33]=[CH:32][CH:31]=[CH:30]3)[CH:25]=[CH:24][CH:23]=1>O>[S:1]([O-:5])([O-:4])(=[O:3])=[O:2].[N:8]1[C:21]2[C:12](=[CH:13][CH:14]=[C:15]3[C:20]=2[N:19]=[CH:18][CH:17]=[CH:16]3)[CH:11]=[CH:10][CH:9]=1.[N:22]1[C:35]2[C:26](=[CH:27][CH:28]=[C:29]3[C:34]=2[N:33]=[CH:32][CH:31]=[CH:30]3)[CH:25]=[CH:24][CH:23]=1.[Cu+2:6]

참가 물질

5

반응물 3

HCID 13181,10-Phenanthroline2회HCID 212261,10-Phenanthroline hydrateHCID 24462Copper Sulfate

생성물 1

HCID 69646830Copper Bis(1,10-phenanthroline) Sulfate

시약·촉매·용매 1

HCID 962Water용매

실험 절차

The following describes the preparation of a 10 mM stock solution of Cu(phenanthroline)2SO4. To a 100 mL of distilled water, in an Erlenmeyer flask, was added 162 mg (1.0 mmol) of anhydrous copper sulfate (Aldrich Chemical Company, Inc., Milwaukee, Wis.). The solid immediately caked into pale blue chunks on the bottom of the Erlenmeyer flask. Upon swirling of the Erlenmeyer flask, these pale blue chunks slowly dissolved. To this solution was added 399 mg (2.0 mmol) of 1,10-phenanthroline hydrate (Aldrich Chemical Company, Inc. supra.). At this point, there were needles of phenanthroline floating atop the aqueous suspension. These needles of phenanthroline were dissolved by sonication for 5 minute in a Branson M2200 sonicator. The resulting solution was an aquamarine blue, 10 mM solution of Cu(phenanthroline)2SO4. Using a Beckman DU70 spectrophotometer, the A720 of this solution was found to be 0.61 O.D.

후처리

  1. dissolutionthese pale blue chunks slowly dissolved

출처 및 근거

ORD 기록
ord-df58b9f7bf25490fae13f15615976821
출처 데이터셋
uspto-grants-1999_01
특허 번호
US05858650

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