Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
12-Methoxydodecanoate → 12-Methoxydodecanoyl chloride
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 12-Methoxydodecanoate | HCID 1420 | — |
| 반응물 | Oxalyl chloride | HCID 65578 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | 12-Methoxydodecanoyl chloride | HCID 19611759 | 99.9% |
반응 단계
Oxalyl chloride (16.0 g, 70 mmol) was added dropwise to a solution of 12-methoxydodecanoic acid (9.8 g, 77 mmol) in 300 mL of anhydrous toluene. After stirring at room temperature for 16 hours the solvent was removed on a rotary evaporator. The residue was taken up in anhydrous toluene and concentrated to give the title compound (17.4 g) as a yellow liquid. The structure was verified by infrared spectroscopy (1796 cm-1) and NMR.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05859052 |
| 출처 데이터셋 | uspto-grants-1999_01 |
| ORD ID | ord-826b2a5b37604c488655ae23e4757607 |
| 출처 메모 | uspto-grants-1999_01 |