Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Formic Acid → (E)-but-2-enedioic acid;copper
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Formic Acid | HCID 284 | — |
| 반응물 | Fumaric Acid | HCID 444972 | — |
| 반응물 | Formic acid, copper salt | HCID 44152240 | — |
| 용매 | Methanol | HCID 887 | — |
| 생성물 | (E)-but-2-enedioic acid;copper | HCID 90471545 | 45.7% |
반응 단계
1.74 g of fumaric acid was dissolved in a mixture solvent having 100 cm3 of methanol and 8 cm3 of formic acid. Then, under stirring at the normal temperature, into the above solution, a further solution in which 3.38 g of formic acid copper was dissolved in 100 cm3 of methanol was dripped. After this solution was left still for one day, the precipitation product was suction-filtered and dried for 120° C./4 hours, whereby 1.23 g of fumaric acid copper was obtained. This substance had the specific surface area of 480 m2 /g.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05862796 |
| 출처 데이터셋 | uspto-grants-1999_01 |
| ORD ID | ord-aa4934b717674c5d9fe39db460c9e43a |
| 출처 메모 | uspto-grants-1999_01 |