Allyl Alcohol → 9,10-Dihydro-9,10-ethanoanthracene-11-methanol

HRID 345017노트

반응식

HRID 345017 반응식
[CH:1]1[C:14]2[C:5](=[CH:6][C:7]3[C:12]([CH:13]=2)=[CH:11][CH:10]=[CH:9][CH:8]=3)[CH:4]=[CH:3][CH:2]=1.[CH2:15]([OH:18])[CH:16]=[CH2:17]>C1C=CC=CC=1>[CH:4]1[C:5]2[CH:6]3[CH2:17][CH:16]([CH2:15][OH:18])[CH:13]([C:12]4[C:7]3=[CH:8][CH:9]=[CH:10][CH:11]=4)[C:14]=2[CH:1]=[CH:2][CH:3]=1

참가 물질

4

반응물 2

HCID 7858Allyl AlcoholHCID 8418Anthracene

생성물 1

HCID 2443799,10-Dihydro-9,10-ethanoanthracene-11-methanol

시약·촉매·용매 1

HCID 241Benzene용매

반응 조건

온도
210 °C

실험 절차

Anthracene (45.4 gm) was combined with allyl alcohol (90.8 gm) and benzene (260 ml) in a Parr bomb and heated to 210° C. for 12 hours. The benzene was removed on a rotary evaporator and the residue was recrystallized from n-heptane to provide the product as a white solid (mp=104-105° C.).

후처리

  1. customThe benzene was removed on a rotary evaporator
  2. customthe residue was recrystallized from n-heptane

출처 및 근거

ORD 기록
ord-26e8b67da6d0439bab031a0b94d37ce5
출처 데이터셋
uspto-grants-1991_10
특허 번호
US05055468

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