Toluene → HCID 86745139, 화합물

HRID 345195

반응식

HRID 345195 반응식
[Cl:1][C:2]([Cl:23])([Cl:22])[C:3]1[N:8]=[C:7]([C:9]([Cl:12])([Cl:11])[Cl:10])[N:6]=[C:5]([C:13]2[CH:21]=[CH:20][C:16]([C:17](Cl)=[O:18])=[CH:15][CH:14]=2)[N:4]=1.[CH3:24][N:25]1[C:33]2[C:28](=[CH:29][CH:30]=[CH:31][CH:32]=2)[C:27]([CH3:35])([CH3:34])[C:26]1=[CH2:36].C(N(CC)CC)C.C1(C)C=CC=CC=1>CCOCC.O>[Cl:11][C:9]([Cl:12])([Cl:10])[C:7]1[N:8]=[C:3]([C:2]([Cl:1])([Cl:22])[Cl:23])[N:4]=[C:5]([C:13]2[CH:21]=[CH:20][C:16]([C:17]([CH:36]=[C:26]3[C:27]([CH3:34])([CH3:35])[C:28]4[C:33](=[CH:32][CH:31]=[CH:30][CH:29]=4)[N:25]3[CH3:24])=[O:18])=[CH:15][CH:14]=2)[N:6]=1

참가 물질

7

반응물 4

HCID 1140TolueneHCID 83511,3,3-Trimethyl-2-methyleneindolineHCID 8471TriethylamineHCID 14473251HCID 14473251, 화합물

생성물 1

HCID 86745139HCID 86745139, 화합물

시약·촉매·용매 2

HCID 962Water용매HCID 3283Diethyl Ether용매

실험 절차

4-(4,6-Bis-trichloromethyl-s-triazin-2-yl)benzoylchloride (15.4 pbw) are added dropwise with stirring at 10° C. to 5.2 pbw of 1,3,3-trimethyl-2-methylene-indoline and 10.6 pbw of triethylamine in 140 pbw of anhydrous toluene. The mixture is stirred for 3 hours at room temperature. It is then admixed with 100 pbw of water and 200 pbw of ether and extracted by shaking. The dried organic phase is concentrated. The residue is recrystallized from 2-methoxy-ethanol, giving red-orange crystals.

후처리

  1. extractionextracted
  2. stirringby shaking
  3. concentrationThe dried organic phase is concentrated
  4. customThe residue is recrystallized from 2-methoxy-ethanol
  5. customgiving red-orange crystals

출처 및 근거

ORD 기록
ord-0e364f3de92147eebb472fe12c1927e9
출처 데이터셋
uspto-grants-1991_10
특허 번호
US05055579

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