3-(2-Trimethylsilyl-4-furyl)propan-1-ol → 3-(2-Trimethylsilyl-4-furyl)propan-1-al

HRID 345883노트

반응식

HRID 345883 반응식
[Cr](Cl)([O-])(=O)=O.[NH+]1C=CC=CC=1.[CH3:12][Si:13]([CH3:24])([CH3:23])[C:14]1[O:15][CH:16]=[C:17]([CH2:19][CH2:20][CH2:21][OH:22])[CH:18]=1>C(Cl)Cl>[CH3:24][Si:13]([CH3:12])([CH3:23])[C:14]1[O:15][CH:16]=[C:17]([CH2:19][CH2:20][CH:21]=[O:22])[CH:18]=1

참가 물질

4

반응물 2

HCID 150370913-(2-Trimethylsilyl-4-furyl)propan-1-olHCID 178418287HCID 178418287, 화합물

생성물 1

HCID 150370923-(2-Trimethylsilyl-4-furyl)propan-1-al

시약·촉매·용매 1

HCID 6344Dichloromethane용매2회

실험 절차

To a stirring mixture of pyridinium chlorochromate (3.89 g, 18.03 mmol) suspended in methylene chloride (100 ml) at 0° was added 3-(2-trimethylsilyl-4-furyl)propan-1-ol (1.19 g. 6.01 mmol), prepared as in Example 2, in dry methylene chloride (15 ml). This mixture was allowed to warm to room temperature, stirred for 90 minutes, filtered and concentrated to give the desired aldehyde.

후처리

  1. additionwas added
  2. filtrationfiltered
  3. concentrationconcentrated

출처 및 근거

ORD 기록
ord-395fd4e17bc942579f2255cdc7cdaab9
출처 데이터셋
uspto-grants-1991_10
특허 번호
US05059611

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