Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Acetic Acid → 2-Furyltrimethylsilane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Acetic Acid | HCID 176 | — |
| 반응물 | Piperidine | HCID 8082 | — |
| 반응물 | 3-(2-Trimethylsilyl-4-furyl)propan-1-al | HCID 15037092 | — |
| 반응물 | 2,2-Dioctylpropanedioate | HCID 22059025 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | 2-Furyltrimethylsilane | HCID 137092 | — |
반응 단계
3-(2-Trimethylsilyl-4-furyl)propan-1-al is reacted with dioctylmalonate in tetrahydrofuran in the presence of acetic acid and piperidine to give 3-[4,4-di (carbooctanoxy)-3-butenyl]- 5-trimethylsilylfuran which is treated with cold aqueous potassium hydroxide to give 3-(4-carboxy-4-carbooctanoxy-3-butenyl)-5-trimethylsilylfuran.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05059611 |
| 출처 데이터셋 | uspto-grants-1991_10 |
| ORD ID | ord-f22021f889e543469ccef2e7d86fe91e |
| 출처 메모 | uspto-grants-1991_10 |