Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
m-Chloroperbenzoic acid → 4-(4-(2-Quinolinylmethylsulfinyl)phenoxymethyl)benzoic acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | m-Chloroperbenzoic acid | HCID 70297 | — |
| 반응물 | Potassium Bicarbonate | HCID 516893 | — |
| 반응물 | 4-(4-(2-Quinolinylmethylthio)phenoxymethyl)benzoic acid | HCID 14774160 | — |
| 용매 | 1,2-Dichloroethylene | HCID 10900 | — |
| 생성물 | 4-(4-(2-Quinolinylmethylsulfinyl)phenoxymethyl)benzoic acid | HCID 14774161 | — |
반응 단계
4-(4-(2-quinolinylmethylthio)phenoxymethyl)benzoic acid (4 mmol) in dichloroethene (50 ml) is stirred with m-chloroperbenzoic acid (4 mmol) and solid potassium hydrogen carbonate (1.0 g). The reaction is assayed by TLC and upon consumption of the starting thio compound, the mixture is filtered, washed with dilute aqueous sodium bisulfite, dried and evaporated to give 4-(4-(2-quinolinylmethylsulfinyl)phenoxymethyl)benzoic acid.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05059610 |
| 출처 데이터셋 | uspto-grants-1991_10 |
| ORD ID | ord-54e328f7401f469a93cbcf62da657876 |
| 출처 메모 | uspto-grants-1991_10 |