Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ethylene → 1-(2-Bromoethyl)-3,5-dimethyl Adamantane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ethylene | HCID 6325 | — |
| 반응물 | 1-Bromo-3,5-dimethyladamantane | HCID 98317 | — |
| 반응물 | Bromhydrol | HCID 166749 | — |
| 용매 | Hexane | HCID 8058 | — |
| 생성물 | 1-(2-Bromoethyl)-3,5-dimethyl Adamantane | HCID 15068767 | 48% |
반응 단계
Mix 1.4 mol of 1-bromo-3,5-dimethyl adamantane (I) in hexane with 0.6 mol of aluminum bromide at -75° C. Subsequently, pass ethylene through the solution for 20-30 minutes, stir for 5 min., and pour the reaction mixture onto ice water. Extract with ether, dry the organic phase and evaporate to dryness. Recrystallize the residue from methanol. (Yield: 48%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05061703 |
| 출처 데이터셋 | uspto-grants-1991_10 |
| ORD ID | ord-8ea37ed7204243fe814166548c4d8d15 |
| 출처 메모 | uspto-grants-1991_10 |