Acetone → 4-(Bromomethyl)-2,2-dimethyl-1,3-dioxolane

HRID 34692

반응식

[Br:1][CH2:2][CH:3]([OH:6])[CH2:4][OH:5].S([O-])([O-])(=O)=O.[Mg+2].[CH3:13][C:14]([CH3:16])=O>>[CH3:13][C:14]1([CH3:16])[O:6][CH:3]([CH2:2][Br:1])[CH2:4][O:5]1

참가 물질

반응물 3

HCID 180Acetone

HCID 208273-Bromo-1,2-propanediol

HCID 24083Sulfuric acid magnesium salt (1:1)

생성물 1

HCID 1697594-(Bromomethyl)-2,2-dimethyl-1,3-dioxolane

실험 절차

An acetone solution of bromomethyl ethylene glycol is refluxed for 24 hours in the presence of anhydrous magnesium sulfate. The cooled reaction mixture is filtered and the solvent is removed to provide a residual crude product.

후처리

customThe cooled reaction mixture
filtrationis filtered
customthe solvent is removed

출처 및 근거

ORD 기록: ord-01f407b26c404daab6db59143a8e4364
출처 데이터셋: uspto-grants-1988_08
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04762912

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